Chapter 25 Multifunctional Compounds: Carbohydrates

Carbohydrates are multifunctional compounds that contain several hydroxyl units as well as a ketone, aldehyde, or a carboxyl unit. Carbohydrates are important in mammalian biology, as well as in the biology of plants and insects. Glycosides are molecules in which a sugar is bound to another substructure via a glycosidic bond. Nucleosides are the structural subunit of nucleic acids such as DNA and RNA. Nucleosides have a ribose unit and a pyrimidine or a purine nucleobase. Glycoses are chiral aldehyde-alcohol or chiral ketone-alcohol carbohydrates that are usually monosaccharides. Pentose and hexose derivatives form cyclic hemiacaetals. An amino sugar is a molecule in which a hydroxyl group has been replaced with an amine group.

Monosaccharides

Furanoses and Pyranoses

Anomeric Centers

Mutarotation

Ketone Monosaccharides

Disaccharides and Trisaccharides

Reactions of Carbohydrates

Nucleotides and Nucleosides

RNA and DNA

Amino Sugars

Glycans and Glycosides